BASICITY OF SILATRANES

Authors

  • М. Г. Воронков A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences
  • В. В. Беляева A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences
  • К. А. Абзаева A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences

DOI:

https://doi.org/10.1007/1341

Keywords:

silatranes, complexation center, coordination bond, electronegativity, nucleophilicity, proton acceptor, silatrane basicity

Abstract

The silatranes basicity study results are summarized. A large amount of experimental data obtained 25-40 years ago is critically reviewed. It is shown that the reactivity and physicochemical properties of silatranes are determined by their basicity, which depends on the stereoelectronic structure.

Authors: M. G. Voronkov, V. V. Belyaeva, and K. A. Abzaeva.

English translation in Chemistry of Heterocyclic Compounds, 2011, 47 (11), pp 1330-1338

http://link.springer.com/article/10.1007/s10593-012-0918-1

Downloads

Published

2013-12-11

Issue

No. 11 (2011)

Section

Review Articles