DIRECTION OF THE HETEROCYCLIZATION REACTION OF 3-ALLYL- AND 3-PROPARGYLSULFANYL-5<i>H</i>-[1,2,4]TRIAZINO[5,6-<i>b</i>]INDOLES

Authors

  • А. В. Рыбакова Southern Ural State University
  • П. А. Слепухин I. Ya. Postovskii Institute of Organic Synthesis, Ural Branch, Russian Academy of Sciences
  • Д. Г. Ким Southern Ural State University

DOI:

https://doi.org/10.1007/377

Keywords:

3-allylsulfanyl-5H-[1, 2, 4]triazino[5, 6-b]indole, methylidene-2, 3-dihydro[1, 3]thiazolo[1, 6-b]indoles, methyl[1, 3-propargylsulfanyl-5H-[1, heterocyclization, iodocyclization, X-ray structural analysis

Abstract

It has been established by X-ray structural analysis that the iodocyclization of 3-allylsulfanyl-5H-[1,2,4]triazino[5,6-b]indole occurs at the N-2 atom. It was shown that heterocyclization of 3-propargylsulfanyl-5H-[1,2,4]triazino[5,6-b]indoles proceeds in the presence of alkali at the N-2 atom but under the action of sulfuric acid at the N-4 atom.

Authors: A. V. Rybakova, P. A. Slepukhin, and D. G. Kim.

English Translation in Chemistry of Heterocyclic Compounds, 2013, 49 (8), pp 1232-1236

http://link.springer.com/article/10.1007/s10593-013-1367-1

Author Biographies

А. В. Рыбакова, Southern Ural State University

Анастасия Владимировна Рыбакова

преподаватель кафедры "Органическая химия"

П. А. Слепухин, I. Ya. Postovskii Institute of Organic Synthesis, Ural Branch, Russian Academy of Sciences

Павел Александрович Слепухин

Старший научный сотрудник

Д. Г. Ким, Southern Ural State University

Дмитрий Гымнанович Ким

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Published

2013-06-17

Issue

No. 8 (2013)

Section

Original Papers