3-CYANO-4,6-DIMETHYL-5-R-PYRIDINE-2-SULFONYL CHLORIDES AND N-SUBSTITUTED SULFONYLAMIDES BASED ON THEM
DOI:
https://doi.org/10.1007/6579Keywords:
sulfonylamides, sulfonyl chlorides, oxidative chlorination, synthesis, eliminationAbstract
3-Cyanopyridine-2-sulfonyl chlorides were synthesized by the oxidative chlorination of the respective 3-cyanopyridine-2(1H)-2-thiones. It was established that 3-cyano-4,6-dimethylpyridine-2-sulfonyl chloride eliminates a SO2 molecule at the isolation stage. N-Substituted sulfonylamides based on the latter were obtained by the reaction of the crude sulfonyl chloride with amines in an aqueous medium.
How to Cite
Dmitrieva, I. G.; Dyadyuchenko, L. V.; Strelkov, V. D.; Kaigorodova, E. A. Chem. Heterocycl. Compd. 2009, 45, 1047. [Khim. Geterotsikl. Soedin. 2009, 1311.]
For this article in the English edition see DOI 10.1007/s10593-009-0386-4