TAUTOMERISM IN THE SERIES OF PYRROLO[2,3-<i>h</i>]-, -[3,2-<i>f</i>]-, -[2,3-<i>f</i>]-, -[3,2-<i>g</i>]-, AND -[3,2-<i>h</i>]-QUINOLINES

Authors

  • С. А. Ямашкин M. E. Evsevyev Mordov State Pedagogical Institute, Saransk 43007
  • Е. А. Алямкина M. E. Evsevyev Mordov State Pedagogical Institute, Saransk 43007

DOI:

https://doi.org/10.1007/6590

Keywords:

pyrroloquinolines, calculated and experimental <sup>1</sup>H NMR spectra of pyrroloquinolines, tautomerism in a series of pyrroloquinolines, quinoline and hydroxyquinoline forms, chemical shifts of protons of β-H hydroxyquinoline and β-H quinoline

Abstract

Molecules of pyrroloquinolines obtained from substituted 4-, 5-, 6-, and 7-aminoindoles and  β-keto esters (acetoacetic, trifluoroacetoxy, and oxaloacetic esters) in quinoline and hydroxyquinoline forms have been investigated by semi-empirical calculations. On the basis of the experimental data and the calculated  1H NMR spectra spectral criteria have been found for the assignment to one or the other tautomeric form.

How to Cite
Yamashkin, S. A.; Alyamkina, E. A.  Chem. Heterocycl. Compd. 2009, 45, 1121. [Khim. Geterotsikl. Soedin. 2009, 1400.]

For this article in the English edition see DOI 10.1007/s10593-009-0399-z

 

Published

2022-02-14

Issue

Section

Original Papers