SYNTHESIS AND TRANSFORMATIONS OF SUBSTITUTED 4,6-DIMETHYLPYRAZOLO[3,4-<i.b</i>]PYRIDYL-3-AZIDES AND -SULFONYL CHLORIDES

Authors

  • И. Г. Дмитриева Kuban State Agrarian University, Krasnodar 350044
  • Л. В. Дядюченко All-Russian Research Institute of Biological Plant Protection, Krasnodar 350039
  • В. Д. Стрелков All-Russian Research Institute of Biological Plant Protection, Krasnodar 350039
  • Е. А. Кайгородова Kuban State Agrarian University, Krasnodar 350044

DOI:

https://doi.org/10.1007/7219

Keywords:

azides, pyrazolo[3, 4-b]pyrimidines, sulfonylamides, sulfonyl chlorides, diazotization, substitution, mass spectra, synthesis, elimination

Abstract

Diazotization of the amino group of 3-amino-4,6-dimethylpyrazolo[3,4-b]pyrimidines and subsequent replacement of the diazo group in the formed  diazonium chlorides by an azide group gave the corresponding 3-azido derivatives. Their reactions  with  active methylene compounds have been studied. Substitution of the diazo group by a sulfo group gave the related 4,6-dimethylpyrazolo-[3,4-b]pyridyl-3-sulfonyl chlorides and sulfonylamides.

How to Cite
Dmitrieva, I. G.; Dyadyuchenko, L. V.; Strelkov, V. D.; Kaigorodova, E. A.  Chem. Heterocycl. Compd. 2008, 44, 1267. [Khim. Geterotsikl. Soedin. 2008, 1556.]

For this article in the English edition see DOI 10.1007/s10593-009-0169-y


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Published

2022-11-25

Issue

No. 10 (2008)

Section

Original Papers