SYNTHESIS OF N-SUBSTITUTED 9-[2-(3,4-METHYLENEDIOXYPHENYL)-2-OXOETHYL]-1,5-DINITRO-7,8-BENZO-3-AZABICYCLO[3.3.1]NON-7-EN-6-ONES

Authors

  • И. Е. Якунина L. N. Tolstoi Tula State Pedagogical University, Tula 300026
  • Ю. М. Атрощенко L. N. Tolstoi Tula State Pedagogical University, Tula 300026
  • И. В. Шахкельдян L. N. Tolstoi Tula State Pedagogical University, Tula 300026
  • К. И. Кобраков A. N. Kosygin Moscow State Textile University, Moscow 117918
  • Н. А. Троицкий N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow 119991
  • О. И. Бойкова L. N. Tolstoi Tula State Pedagogical University, Tula 300026

DOI:

https://doi.org/10.1007/7400

Keywords:

3-azabicyclo[3.3.1]nonanes, anionic Yanovskii adducts, homo- and heteronuclear correlation spectroscopy, aminomethylation reaction, Mannich reaction

Abstract

Aminomethylation has been accomplished of the anionic Yanovskii adduct of 2,4-dinitronaphthol and 3,4-dimethylenedioxyacetophenone. The structure of the 3-substituted 9-[2-(3,4-methylenedioxyphenyl)-2-oxoethyl]-1,5-dinitro-7,8-benzo-3-azabicylo[3.3.1]non-7-en-6-one was  determined by two-dimensional homo- and heteronuclear correlation spectroscopy.

How to Cite
Yakunina, I. E.; Atroshchenko, Yu. M.; Shahkheldyan, I. V.; Kobrakov, K. I.; Troizkiy, N. A.; Boikova, O. I.  Chem. Heterocycl. Compd. 2007, 43, 1174. [Khim. Geterotsikl. Soedin. 2007, 1382.]

For this article in the English edition see DOI 10.1007/s10593-007-0180-0


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Published

2023-01-30

Issue

No. 9 (2007)

Section

Original Papers