<i>sym</i>-TRIAZINES. 7. HYDROLYSIS AND CYCLIZATION OF 1,3,5-TRIAZINE SERIES MONONITRILES

Authors

  • С. Н. Михайличенко Kuban State Agricultural University, Krasnodar 350044
  • А. А. Чеснюк Kuban State Agricultural University, Krasnodar 350044
  • Л. Д. Конюшкин Kuban State Agricultural University, Krasnodar 350044
  • С. И. Фирганг N. D. Zelinsky Institute for Organic Chemistry, Russian Academy of Sciences, Moscow 117913
  • В. Н. Заплишный Kuban State Agricultural University, Krasnodar 350044

DOI:

https://doi.org/10.1007/7985

Keywords:

2-carbamoyl-sym-triazines, 2-[tetrazol-5-yl]-sym-triazines, 6H-sym-triazines, 2-cyano-sym-triazines

Abstract

The routes of base and acid hydrolysis of sym-triazine mononitriles has been studied for aqueous or aqueous-alcohol media. Depending on the pH of the  medium, the concentration of reagents, and the temperature it was found that the hydrolysis led  to the formation of amides, oxo or alkoxy 1,3,5-triazines, or to an unstable sym-triazine carboxylic acid, the latter leading to formation of substituted sym-triazines. A novel series of tetrazolyltriazines has been prepared by the reaction of the mononitriles with sodium azide and their alkylation has been studied.

How to Cite
Mikhailichenko, S. N.; Chesnyuk, A. A.; Konyushkin, L. D.; Firgang, S. I.; Zaplishny, V. N.  Chem. Heterocycl. Compd. 2006, 42, 642. [Khim. Geterotsikl. Soedin. 2006, 731.]

For this article in the English edition, see DOI 10.1007/s10593-006-0140-0

 

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Published

2023-08-22

Issue

No. 5 (2006)

Section

Original Papers