INVESTIGATIONS ON 2,3'-BIQUINOLYLS. 12. ALKYLATION AND ARYLATION OF 2,3'-BIQUINOLYL DIANION WITH ORGANOMETALLIC COMPOUNDS. NEW TYPE OF REACTION FOR DIANIONS OF AROMATIC COMPOUNDS
Keywords:
2,3'-biquinolyl, dianion, 1',2'-dihydro-2,3'-biquinolyls, organolithium compounds, alkylation, arylation, nucleophilic substitution, one-electron transferAbstract
2,3'-Biquinolyl dianion reacts with organolithium and organomagnesium compounds with the formation, after treatment of the reaction mixture with water, of 2'-alkyl(aryl)-1',2'-dihydro-2,3'-biquinolyls, and, after treatment of the reaction mixture with alkyl halides, of 1'-alkyl-2'-alkyl(aryl)-1',2'-dihydro-2,3'-biquinolyls. The reaction includes attack of the nucleophilic reagent with an electron transfer to a molecule of solvent.
How to Cite
Aksenov, A. V.; Aksenova, I. V.; Smushkevich, Yu. I. Chem. Heterocycl. Compd. 2001, 37, 976. [Khim. Geterotsikl. Soedin. 2001, 1065.]
For this article in the English edition, see DOI https://doi.org/10.1023/A:1012735500872
