SYNTHESIS OF MONOOXIMES OF 3,3-DIALKYL-3,4-DIHYDRO-1-ISOQUINOLYL ARYL KETONES AND DIKETONES

Authors

  • B. А. Глyшков Institute of Technical Chemistry, Urals Branch, Russian Academy of Sciences, Perm 614600
  • B. И. Карманов Institute of Technical Chemistry, Urals Branch, Russian Academy of Sciences, Perm 614600
  • E. B. Фешина Institute of Technical Chemistry, Urals Branch, Russian Academy of Sciences, Perm 614600
  • Г. А. Постаногова Institute of Technical Chemistry, Urals Branch, Russian Academy of Sciences, Perm 614600
  • Ю. B. Шкляев Institute of Technical Chemistry, Urals Branch, Russian Academy of Sciences, Perm 614600

Keywords:

aroylacetonitriles, isoquinoline, oximes, nitrosylation, Ritter reaction

Abstract

1-Aroylmethyl-3,3-dialkyl-3,4-dihydroisoquinolines were synthesized by the Ritter reaction. The nitrosylation of these isoquinoline derivatives proceeds smoothly at the β-enamine carbon atom to give monooximes of 3,3-dialkyl-3,4-dihydro-1-isoquinolyl aryl diketones. Loss of an acetyl group occurs in the nitrosylation of 1-(α-acetylbenzyl)-3,3-dimethyl-3,4-dihydroisoquinoline.

How to Cite
Glushkov, V. A.; Karmanov, V. I.; Feshina, E. V.; Postanogova, G. A.; Shklyaev, Yu. V. Chem. Heterocycl. Compd. 2001, 37, 103. [Khim. Geterotsikl. Soedin. 2001, 108.]

For this article in the English edition, see DOI https://doi.org/10.1023/A:1017549102961

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Published

2001-01-25

Issue

No. 1 (2001)

Section

Original Papers