REVEALED AND HIDDEN ASPECTS OF HYDROBORATION BY OXAZOLINE COBALT COMPLEXES

Authors

  • Ilona V. Raspertova Taras Shevchenko National University of Kyiv, 64/13 Volodymyrska St., Kyiv 01601 https://orcid.org/0000-0002-2382-063X
  • Dmytro M. Khomenko Taras Shevchenko National University of Kyiv, 64/13 Volodymyrska St., Kyiv 01601. Enamine Ltd., 78 Winston Churchill St., Kyiv 02094
  • Oleksandr V. Vashchenko Taras Shevchenko National University of Kyiv, 64/13 Volodymyrska St., Kyiv 01601
  • Rostyslav D. Lampeka Taras Shevchenko National University of Kyiv, 64/13 Volodymyrska St., Kyiv 01601

Keywords:

hydroboration, oxazoline, cobalt catalyst, alkene, alkyne

Abstract

This mini-review explores recent advances in the application of cobalt-based catalysts, which are considered cost-effective and earth-abundant alternatives to noble metals, in carbon–boron bond-forming transformations. Particular attention is paid to systems with oxazoline-based ligands, which have demonstrated high activity and selectivity in hydroboration reactions. The data summarized here highligt the potential of these coordination complexes for further rational ligand design based on oxazoline frameworks, paving the way for their wider application in fine organic synthesis.

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Published

2026-02-24

Issue

Vol. 61 No. 9/10 (2025): Modern catalytic approaches for the assembly and functionalization of heterocyclic compounds

Section

Review Articles