On the reaction of 2-phenylaminothiazoline with α-halogenoketones

Authors

  • А. М. Демченко Chernigov Technological Institute, Chernigov 250027
  • В. А. Чумаков Chernigov Technological Institute, Chernigov 250027
  • А. H. Крaсoвский Chernigov Technological Institute, Chernigov 250027
  • В. В. Пироженко Chernigov Technological Institute, Chernigov 250027
  • М. O. Лозинский Chernigov Technological Institute, Chernigov 250027

Abstract

It was established that the alkylation of 2-phenylaminothiazoline with substituted phenacyl bromides proceeds at the exocyclic nitrogen atom with the formation of 5-aryl-7-phenyl-2,3-dihydroimidazo[2,1-b]thiazolium bromides. In order to confirm the structure of the last, the reductive desulfurization of one of them (Ar=p-chlorophenyl) was accomplished using Raney nickel. It was shown that dequaternization of the resulting 1-phenyl-3-ethyl-4-(p-chlorophenyl)imidazolium bromide to 1-phenyl-4-(p-chlorophenyl)imidazole, identical to the sample obtained by direct synthesis, thereby occurs.

How to Cite
Demchenko, A. M.;, Chumakov, V. A.; Krasovskii, A. N.; Pirozhenko, V. V.; Lozinskii, M. O. Chem. Heterocycl. Compd. 1997, 33, 724. [Khim. Geterotsikl. Soedin. 1997, 829.]

For this article in the English edition, see DOI https://doi.org/10.1007/BF02291807

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Published

1997-06-25

Issue

No. 6 (1997)

Section

Original Papers