1,3-Thiazepines 4. Reactions of 2-iminothiazepines with methyl acrylate. Crystal and molecular structure of 2-phenylimino-3-(β-methoxycarbonylethyl)- and 2-benzyliminohexahydro-1,3-thiadiazepines

Authors

  • P. Ф. Амбарцумова Institute of Plant Chemistry, Uzbek Academy of Sciences, Tashkent 700170
  • Б. Ташходжаев Institute of Plant Chemistry, Uzbek Academy of Sciences, Tashkent 700170
  • M. К. Махмудов Institute of Plant Chemistry, Uzbek Academy of Sciences, Tashkent 700170

Abstract

Addition of 2-aryliminohexahydro-1,3-thiazepines to methyl acrylate occurs with participation of the endocyclic nitrogen atom. Structures of the products have been established by IR and mass spectroscopy and x-ray diffraction. The previously described 2-benzylaminotetrahydro-1,3-thiazepine is in fact 2-benzyliminohexahydro-1,3-thiazepine.

How to Cite
Ambartsumova, R. F.; Tashkhodzhaev, B.; Makhmulov, M. K. Chem. Heterocycl. Compd. 1997, 33, 475. [Khim. Geterotsikl. Soedin. 1997, 554.]

For this article in the English edition, see DOI https://doi.org/10.1007/BF02321396

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Published

2025-10-22

Issue

No. 4 (1997)

Section

Original Papers