Free radicals in the electrochemical reduction of 1,2-dihydro-3-nitropyridine derivatives

Authors

  • Я. Страдынь Latvian Institute of Organic Synthesis, Riga LV-1006
  • P. Гаварс Latvian Institute of Organic Synthesis, Riga LV-1006
  • Л. Баумане Latvian Institute of Organic Synthesis, Riga LV-1006
  • Б. Виганте Latvian Institute of Organic Synthesis, Riga LV-1006
  • Г. Дубурс Latvian Institute of Organic Synthesis, Riga LV-1006

Abstract

The formation of primary radical anions of N-substituted 1,2-dihydro-3-nitropyridines was confirmed by the ESR method under conditions of electrochemical generation of free radicals, and their structure was established. The causes of the different ability of 1,2- and 1,4-dihydro-3-nitropyridines to form free radicals during electrochemical reduction that are stable enough to be studied by the ESR method are examined.

How to Cite
Stradyn', Y.; Gavars, R.; Baumane, L.; Vigante, B.; Duburs, G. Chem. Heterocycl. Compd. 1996, 32, 1047. [Khim. Geterotsikl. Soedin. 1996, 1222.]

For this article in the English edition, see DOI https://doi.org/10.1007/BF01164710

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Published

1996-09-25

Issue

No. 9 (1996)

Section

Original Papers