Fluorobenzo-1,4-thiazine oxides from bis(vinylsulfinyl)- and bis(vinylsulfonyl)fluorobenzenes and 2-aminoethanol

Authors

  • C. В. Амoсова Irkutsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, Irkutsk
  • В. И. Гостевская Irkutsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, Irkutsk
  • Г. М. Гаврилова Irkutsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, Irkutsk
  • B. H. Нестеров Irkutsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, Irkutsk
  • Ю. T. Стручков Irkutsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, Irkutsk
  • Л. Н. Ильичева Irkutsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, Irkutsk

Abstract

It has been established that 1,2,4,5-tetrafluoro-3, 6-bis(vinylsulfinyl)- and 1,2,4,5-tetrafluoro-3,6-bis(vinylsulfonyl)benzenes react with 2-aminoethanol by nucleophilic addition at the activated double bond with replacement of fluorine atoms on the benzene ring by the amino group of 2-aminoethanol to give 4,9-bis(2-hydroxyethyl)-5,10-difluoro-1,2,3,4,6,7,8,9-octahydrobenzo[1,2-b;5,4-b]di-1,4-thiazine 1,6-dioxide and 1,1,6,6-tetraoxide respectively.

How to Cite
Amosova, S. V.; Gostevskaya, V. I.; Gavrilova, G. M.; Nesterov, V. N.; Struchkov, Yu. T.; Il'icheva L. N. Chem. Heterocycl. Compd. 1996, 32, 1023. [Khim. Geterotsikl. Soedin. 1996, 1195.]

For this article in the English edition, see DOI https://doi.org/10.1007/BF01164706

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Published

1996-09-25

Issue

No. 9 (1996)

Section

Original Papers