Highly polarized enamines. 2. Synthesis and investigation of the further amination of derivatives of α,α-diamino-β-cyano-β-nitroethylene

Authors

  • В. А. Мaкаров Center for the Chemistry of Medicinals, All-Russian Chemico-Pharmaceutical Scientific Research Institute, Moscow 119815
  • А. Л. Седов Center for the Chemistry of Medicinals, All-Russian Chemico-Pharmaceutical Scientific Research Institute, Moscow 119815
  • O. С. Анисимова Center for the Chemistry of Medicinals, All-Russian Chemico-Pharmaceutical Scientific Research Institute, Moscow 119815
  • B. Г. Гpаник Center for the Chemistry of Medicinals, All-Russian Chemico-Pharmaceutical Scientific Research Institute, Moscow 119815

Abstract

Highly polarized enediamines of the α,α-diamino-β-cyano-β-nitroethylene type have been obtained by the hydrolysis of 4-chloro-5-nitropyrimidines. Several chemical conversions of the enamines obtained have been studied, particularly leading to derivatives of 2-(cyanonitromethylene)imidazoline and -hexahydropyrimidine, and also to derivatives of N, N′-bisvinylpiperazine and 7-methylene-1,4-diazabicyclo(2.2.1]heptane.

How to Cite
Makarov, V. A.; Sedov, A. L.; Anisimova, O. S.; Granik, V. G.  Chem. Heterocycl. Compd. 1996, 32, 699. [Khim. Geterotsikl. Soedin. 1996, 811.]

For this article in the English edition, see DOI https://doi.org/10.1007/BF01164870

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Published

1996-06-25

Issue

No. 6 (1996)

Section

Original Papers