Synthesis of bicyclo-heptane, 6-oxabicyclo-octane and 3-azabicyclo-nonene derivatives in the course of 1,2,4-trimethyl-4-isopropenylcyclohexene cyclization

Authors

  • B. А. Андреев M. V. Lomonosov Moscow State University, Moscow 119899
  • B. Б. Нигматова M. V. Lomonosov Moscow State University, Moscow 119899
  • С. Н. Анфилогова M. V. Lomonosov Moscow State University, Moscow 119899
  • А. А. Бобылева M. V. Lomonosov Moscow State University, Moscow 119899
  • T. И. Пехк nstitute of Chemical and Biological Physics, Estonian Academy of Sciences, Tallin
  • H. А. Беликова M. V. Lomonosov Moscow State University, Moscow 119899

Abstract

Carbocyclic and heterocyclic compounds of the bicyclo[2.2.1]heptane, 6-oxabicyclo[3.2.1]octane, and 3-azabicyclo[3.3.1]nonene series were obtained from the reaction between 1,2,4-trimethyl-4-isopropenylcyclohexene (a dimer of 2,3-dimethylbuta-1, 3-diene) and CH3CN in the presence of H2SO4 which was accompanied by intramolecular cyclization.

How to Cite
Andreev, V. A.; Nigmatova, V. B.; Anfilogova, S. N.; Bobyleva, A. A.; Pekhk, T. I.; Belikova, N. A. Chem. Heterocycl. Compd. 1996, 32, 646. [Khim. Geterotsikl. Soedin. 1996, 754.]

For this article in the English edition, see DOI https://doi.org/10.1007/BF01164862

Published

1996-06-25

Issue

Section

Original Papers