REACTION OF TRIPHENYLSULFONIUM SALT WITH HETARYLLITHIUM REAGENTS

Authors

  • Shigeru Oae Institute of Heteroatom Chemistry, 2509 Hirao, Mihara-cho, 587, Minamikawachi-gun, Osaka
  • Hiroyuki Ishihara Institute of Heteroatom Chemistry, 2509 Hirao, Mihara-cho, 587, Minamikawachi-gun, Osaka
  • Masakuni Yoshihara Institute of Heteroatom Chemistry, 2509 Hirao, Mihara-cho, 587, Minamikawachi-gun, Osaka

Abstract

The reaction of triphenylsulfonium trifluoromethanesulfonate with various nucleophiiic organolithium reagents gave ligand coupling products and the corresponding diaryl or di-heteroaryl sulfides. Moreover, ligand exchange reaction din not give any noticeable product in each reaction. Therefore, it was found that only the ligand coupling reaction proceeds in this reaction system.

How to Cite
Oae, S.; Ishihara, H.; Yoshihara, M. Chem. Heterocycl. Compd. 1995, 31, 917. [Khim. Geterotsikl. Soedin. 1995, 1053.]

For this article in the English edition, see DOI https://doi.org/10.1007/BF01170319

Downloads

Published

1995-08-25

Issue

No. 8 (1995)

Section

Original Papers