Reactions of polyhalopyridines. 8. Reactions of polychlorotrifluoromethyl-pyridines with sodium N,N-dimethyldithiocarbamate. Structure of the 8-trifluoromethylbis-1,3-dithiolo-[4,5-<i>b</i>:4′,5′-<i>e</i>]-pyridine-2,6-dione molecule

Abstract

The reaction of the isomeric tetrachloro-α-, β-, and γ-trifluoromethylpyridines and of 3,4,5-trichloro-2-trifluoromethylpyridine with sodium N,N-dimethyldithiocarbamate dihydrate has been studied. In the case of the α-, and γ-isomers an intramolecular cyclization with the formation of 1,3-dithiol-2-one derivatives occurs and the remaining compounds give only products of mono- or disubstitution of chlorine atoms by a dithiocarbamate fragment at positions 4 or 6 of the pyridine ring. The structure of the compounds synthesized was proved using ¹³C NMR and X-ray crystallographic analysis.

How to Cite
Sipyagin, A. M.; Aliev, Z. G. Chem. Heterocycl. Compd. 1994, 30, 1278. [Khim. Geterotsikl. Soedin. 1994, 1.]

For this article in the English edition, see DOI https://doi.org/10.1007/BF01171176