Phosphorylnitrile oxides. 5. Reactions of 3-(dialkoxyphosphoryl)isoxazoles and -isoxazolines with nucleophilic reagents

Authors

  • В. А. Павлов Institute of Physiologically Active Compounds, Russian Academy of Sciences, Chernogolovka, 1424432, Moscow Oblast
  • А. И. Курдюков Kazan State Technological University, 420015 Kazan
  • Б. И. Горин Kazan State Technological University, 420015 Kazan
  • Ф. P. Сагитова Kazan State Technological University, 420015 Kazan
  • Н. В. Аристова Kazan State Technological University, 420015 Kazan
  • Л. И. Дейко A. I. Gertsen Russian State Pedogogical University, St. Petersburg 191186
  • В. В. Москва Institute of Physiologically Active Compounds, Russian Academy of Sciences, Chernogolovka, 1424432, Moscow Oblast

Abstract

3-Phosphotylated isoxazoles and isoxazolines react with nucleophiles either with cleavage of the P-C bond and subsequent ring opening or with retention of the heterocyclic ring depending on the structure of the ring substituents, nature of the nucleophile, and reaction conditions. This permits the selective chemical modification of the starting compounds.

How to Cite
Pavlov, V. A.; Kurdyukov, A. I.; Gorin, B. I.; Sagitova, F. R.; Aristova, N. V.; Deiko, L. I.; Moskva, V. V.  Chem. Heterocycl. Compd. 1994, 30, 718. [Khim. Geterotsikl. Soedin. 1994, 821.]

For this article in the English edition, see DOI https://doi.org/10.1007/BF01166315

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Published

1994-06-25

Issue

No. 6 (1994)

Section

Original Papers