Inclusion complexes of prochiral heterocyclic ketones with β-cyclodextrins and their reduction with sodium borohydride

Authors

  • Ю. Гольдберг Latvian Institute of Organic Synthesis, Riga LV-1006
  • Э. Абеле Latvian Institute of Organic Synthesis, Riga LV-1006
  • K. Рубина Latvian Institute of Organic Synthesis, Riga LV-1006
  • Ю. Попелис Latvian Institute of Organic Synthesis, Riga LV-1006
  • М. Шиманска Latvian Institute of Organic Synthesis, Riga LV-1006

Abstract

Alkyl(2-furyl), alkyl(2-thienyl), and methyl pyridyl ketones form stoichiometric inclusion complexes with β-cyclodextrins. Reduction of these complexes in aqueous solution of Na2CO3 at room temperature yields the corresponding secondary alcohols with an optical yield which attains 27%.

How to Cite
Gol'dberg, Yu.; Abele, E.; Rubina, K.; Popelis, Yu.; Shimanska, M. Chem. Heterocycl. Compd. 1993, 29, 1399. [Khim. Geterotsikl. Soedin. 1993, 1621.]

For this article in the English edition, see DOI https://doi.org/10.1007/BF00531399

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Published

1993-12-25

Issue

No. 12 (1993)

Section

Original Papers