Reactions of polyhalopyridines 3. Reaction of heptachloro-2-picoline with hydrazine hydrate. structure of the 3,5,6-trichloro-4-hydrazino-2-trichloromethylpyridine molecule

Authors

  • А. М. Сипягин Institute of Chemical Physics at Chernogolovka, Russian Academy of Sciences, Chernogolovka 142432
  • 3. Г. Алиев Institute of Chemical Physics at Chernogolovka, Russian Academy of Sciences, Chernogolovka 142432

Abstract

The reaction of heptachloropicoline with hydrazine hydrate has been studied. The formation of two isomers of hexachlorohydrazinopicoline was discovered corresponding to nucleophilic substitution at positions 2 and 4 of the pyridine ring. The structure of the isomers was determined with the aid of NMR spectroscopy and of X-ray structural analysis.

How to Cite
Sipyagin, A. M.; Aliev, Z. G. Chem. Heterocycl. Compd. 1993, 29, 1287. [Khim. Geterotsikl. Soedin. 1993, 1495.]

For this article in the English edition, see DOI https://doi.org/10.1007/BF00532026

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Published

1993-11-25

Issue

No. 11 (1993)

Section

Original Papers