REARRANGEMENTS OF CYCLOPROPENES INTO FIVE-MEMBERED AROMATIC HETEROCYCLES: MECHANISTIC ASPECT

Authors

  • М. Рубин Department of Chemistry, University of Kansas and Center for Environmentally Beneficial Catalysis
  • П. Г. Рябчук Department of Chemistry, University of Kansas and Center for Environmentally Beneficial Catalysis

DOI:

https://doi.org/10.1007/1307

Keywords:

cyclopropenes, furans, indolizines, pyrroles, transition metal complexes, Lewis acids, catalysis, photochemistry

Abstract

This review covers rearrangements of cyclopropenes into aromatic five-membered heterocyclic compounds, namely furans and pyrroles; accompanied by small ring cleavage proceeding in the presence of catalytic amounts of transition metals, Lewis acids, or under UV irradiation.

Authors: M. Rubin and P. G. Ryabchuk.

English translation in Chemistry of Heterocyclic Compounds, 2012, 48 (1), pp 126-138

http://link.springer.com/article/10.1007/s10593-012-0976-4

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Published

2013-12-05

Issue

No. 1 (2012)

Section

Review Articles