HETEROCYCLIC SUPERBASES: RETROSPECTIVE AND CURRENT TRENDS

Authors

  • А. Ф. Пожарский Southern Federal University
  • В. А. Озерянский Southern Federal University
  • Е. А. Филатова Southern Federal University

DOI:

https://doi.org/10.1007/1314

Keywords:

nitrogen heterocycles, frame heterocycles, phosphazenes, proton sponges, proton traps, basicity, superbasicity

Abstract

The structural principles known to date serving as the basis for the design of heterocyclic compounds with anomalously high basicity (superbasicity) are reviewed. A general classification is given for such superbases as proton sponges, compounds that are similar to proton sponges but are not sponges (proton-sponge-like), and proton traps.

Authors: A. F. Pozharskii, V. A. Ozeryanskii, and E. A. Filatova.

English translation in Chemistry of Heterocyclic Compounds, 2012, 48 (1), pp 200-219

http://link.springer.com/article/10.1007/s10593-012-0983-5

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Published

2013-12-05

Issue

No. 1 (2012)

Section

Review Articles