THE EXTENSION OF CONJUGATED SYSTEM IN PYRIDYL-SUBSTITUTED MONOAZATRIPHENYLENES FOR THE TUNING OF PHOTOPHYSICAL PROPERTIES

Authors

  • Д. С. Копчук Ural Federal University named after the First President of Russia B. N. Yeltsin; I. Ya. Postovskii Institute of Organic Synthesis
  • А. Ф. Хасанов Ural Federal University named after the First President of Russia B. N. Yeltsin
  • И. С. Ковалев Ural Federal University named after the First President of Russia B. N. Yeltsin
  • Г. В. Зырянов Ural Federal University named after the First President of Russia B. N. Yeltsin; I. Ya. Postovskii Institute of Organic Synthesis
  • Г. А. Ким Ural Federal University named after the First President of Russia B. N. Yeltsin; I. Ya. Postovskii Institute of Organic Synthesis
  • И. Л. Никонов Ural Federal University named after the First President of Russia B. N. Yeltsin
  • В. Л. Русинов Ural Federal University named after the First President of Russia B. N. Yeltsin; I. Ya. Postovskii Institute of Organic Synthesis
  • О. Н. Чупахин Ural Federal University named after the First President of Russia B. N. Yeltsin; I. Ya. Postovskii Institute of Organic Synthesis

DOI:

https://doi.org/10.1007/1612

Keywords:

monoazatriphenylene, phenanthrenequinone, aza-Diels–Alder reaction, cross coupling, heterocyclization, luminescence, Suzuki reaction

Abstract

We propose a method for the synthesis of diaryl-substituted pyridylmonoazatriphenylenes by the heterocyclization reaction of dihalosubstituted phenanthrenequinones with pyridine-2-carboxylic acid amidrazone, followed by aza-Diels–Alder reaction and Suzuki cross coupling. The obtained compounds showed more promising photophysical properties, compared to non-arylated analogs.

How to Cite
Kopchuk, D. S.; Khasanov, A. F.; Kovalev, I. S.; Zyryanov, G. V.; Kim, G. A.; Nikonov, I. L.; Rusinov, V. L.; Chupakhin, O. N. Chem. Heterocycl. Compd. 2014, 50, 871. [Khim. Geterotsikl. Soedin. 2014, 943.]

For this article in the English edition see DOI 10.1007/s10593-014-1541-0

Author Biography

Г. В. Зырянов, Ural Federal University named after the First President of Russia B. N. Yeltsin; I. Ya. Postovskii Institute of Organic Synthesis

Григорий Васильевич Зырянов

Старший научный сотрудник, Группа координационных соединений

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Published

2014-07-06

Issue

No. 6 (2014)

Section

Original Papers