SYNTHESIS OF 4-TRIALKYLSILYL(GERMYL)-1<i>H</i>-1,2,3-TRIAZOLECARBALDEHYDE OXIMES

Authors

  • А. С. Медведева A. E. Favorsky Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences
  • М. М. Демина A. E. Favorsky Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences
  • Т. В. Конькова A. E. Favorsky Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences
  • Ч. З. Ву Irkutsk State Technical University
  • Л. И. Ларина A. E. Favorsky Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences

DOI:

https://doi.org/10.1007/1801

Keywords:

element-substituted propynal oximes, propynals, 4-trialkylsilyl(germyl)-1H-1, 2, 3-triazole-5 carbaldehyde oximes, trimethylsilyl azide, 1, 3-dipolar cycloaddition, microwave assistance

Abstract

Methods for the synthesis of 4-trialkylsilyl(germyl)-1H-1,2,3-triazole-5-carbaldehyde oximes have been developed. Microwave activation was shown to be highly efficient in the oximation of 1H-1,2,3-triazole-5-carbaldehydes containing silicon or germanium and also in achieving a multicomponent synthesis of 4-trialkylsilyl-1H-1,2,3-triazole-5-carbaldehyde oxime via the reaction of 3-trimethyl-silylprop-2-yn-1‑al with trimethylsilyl azide and hydroxylamine.

How to Cite
Medvedeva, A. S.; Demina, M. M.; Konkova, T. V.; Vu, T. D.; Larina, L. I. Chem. Heterocycl. Compd. 2014, 50, 967. [Khim. Geterotsikl. Soedin. 2014, 1050.]

For this article in the English edition see DOI 10.1007/s10593-014-1551-y

Author Biographies

А. С. Медведева, A. E. Favorsky Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences

Алевтина Сергеевна Медведева

заведущая лабораторией химии карбофункциональных соединений

М. М. Демина, A. E. Favorsky Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences

Мария Матвеевна Демина

снс

Т. В. Конькова, A. E. Favorsky Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences

Татьяна Владимировна Конькова

нс

Ч. З. Ву, Irkutsk State Technical University

Чан Зыонг Ву

аспирант

Л. И. Ларина, A. E. Favorsky Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences

Людмила Ивановна Ларина

внс

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Published

2014-08-01

Issue

No. 7 (2014)

Section

Original Papers