SYNTHESIS OF NEW PHOTOCHROMIC DIARYLETHENES OF CYCLOPENTENONE SERIES BY NAZAROV REACTION

Authors

  • Валерий З. Ширинян N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Ave., Moscow 119991, Russia
  • Андрей Г. Львов N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Ave., Moscow 119991, Russia
  • Анна М. Янина D. Mendeleev University of Chemical Technology of Russia, 9 Miusskaya Sq., Moscow 125047, Russia
  • Вадим В. Качала N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Ave., Moscow 119991, Russia
  • Михаил М. Краюшкин N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Ave., Moscow 119991, Russia

DOI:

https://doi.org/10.1007/2216

Keywords:

diarylethenes, Lewis acid, , Nazarov reaction, photochromism, quantum yield

Abstract

An effective method is proposed for the synthesis of photochromic diarylethenes of cyclopentenone series with SnCl4-catalyzed
4π-electron cyclization of divinyl ketones by Nazarov reaction as the key step. It was shown that the introduction of an aryl fragment at
position 4 of the cyclopentenone ring significantly improved the quantum yield of diarylethene photocyclization reaction.

How to Cite
Shirinian, V. Z.; Lvov, A. G.; Yanina, A. M.; Kachala, V. V.; Krayushkin, M. Chem. Heterocycl. Compd. 2015, 51, 234. [Khim. Geterotsikl. Soedin. 2015, 51, 234.]

For this article in the English edition see DOI 10.1007/s10593-015-1690-9

Author Biographies

Валерий З. Ширинян, N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Ave., Moscow 119991, Russia

Вед. научн. сотр. ИОХ РАН им. Н. Д. Зелинского (Москва)

Андрей Г. Львов, N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Ave., Moscow 119991, Russia

Научн. сотр., лаборатория гетероциклических соединений, ИОХ РАН

Анна М. Янина, D. Mendeleev University of Chemical Technology of Russia, 9 Miusskaya Sq., Moscow 125047, Russia

Студент, Кафедра химии и технологии органического синтеза РХТУ им. Д. И. Менделеева

Михаил М. Краюшкин, N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Ave., Moscow 119991, Russia

Зав. лабораторией

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Published

2015-03-18

Issue

Vol. 51 No. 3 (2015)

Section

Original Papers