Synthesis and investigation of isomeric mono- and dinitro derivatives of 3-methyl-4-(pyrazol-3-yl)furazan

Authors

  • Игорь Л. Далингер N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
  • Ирина А. Вацадзе N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
  • Татьяна К. Шкинева N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
  • Александр В. Корманов N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
  • Андрей М. Козеев N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
  • Борис Б. Аверкиев A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences; Stockton University
  • Александр И. Далингер M. V. Lomonosov Moscow State University
  • Михаил К. Беклемишев M. V. Lomonosov Moscow State University
  • Алексей Б. Шереметев N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences

DOI:

https://doi.org/10.1007/2450

Keywords:

furazan, nitropyrazole, heteronuclear NMR, nitration, X-ray structural analysis

Abstract

The regioselective introduction of nitro groups in pyrazoles, containing a furazanyl substituent at position 3(5) was investigated. All synthetically accessible isomeric mono- and dinitropyrazole derivatives were obtained. X-ray structural investigation was performed for all mononitroisomers and a dinitro derivative.

How to Cite
Dalinger, I. L.; Vatsadze, I. A.; Shkineva, T. K.; Komarov, A. V.; Kozeev, A. M.; Avrekiev, B. B.; Dalinger, A. I.; Beklemishev, M. K.; Sheremetev, A. B. Chem. Heterocycl. Compd. 2015, 51, 545. [Khim. Geterotsikl. Soedin. 2015, 51, 545.]

For this article in the English edition see DOI 10.1007/s10593-015-1739-9

 

Author Biography

Алексей Б. Шереметев, N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences

Алексей Борисович Шереметев

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Published

2015-07-06

Issue

Vol. 51 No. 6 (2015)

Section

Original Papers