SYNTHESIS AND SPECIAL FEATURES OF THE STRUCTURE OF 6(7)-AMINOPERIMIDINE DERIVATIVES

Authors

  • А. В. Аксенов Stavropol State University
  • А. С. Ляховненко Stavropol State University
  • Н. Ц. Караиванов Stavropol State University
  • И. И. Левина N. M. Emanuel Institute of Biochemical Physics, Russian Academy of Sciences

DOI:

https://doi.org/10.1007/2950

Keywords:

sodium azide, 6(7)-aminoperimidines, perimidine, PPA (polyphosphoric acid), amination, Schmidt reaction

Abstract

A method of synthesizing 6(7)-aminoperimidines has been developed based on the electrophilic amination of perimidines with sodium azide in PPA. The corresponding amides were synthesized by acylation and were also obtained by the Schmidt reaction from 6(7)-acetyl(or benzoyl)perimidines. A special feature of the structure of the 2-substituted amines and amides is the presence of annular tautomerism slow in NMR time.

How to Cite
Aksenov, A. V.l; Lyakhovnenko, A. S.; Karaivanov, N. C.; Levina, I. I. Chem. Heterocycl. Compd. 2010, 46, 468. [Khim. Geterotsikl. Soedin. 2010, 591.]

For this article in the English edition see DOI 10.1007/s10593-010-0532-z

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Published

2016-01-13

Issue

No. 4 (2010)

Section

Original Papers