1,2-DI(4-R-FURAZAN-3-YL)GLYOXIMES: SYNTHESIS BY THE REDUCTION OF 3,4-BIS(4-R-FURAZAN-3-YL)FUROXANS AND STUDY OF THE REACTIVITY OF THESE COMPOUNDS

Authors

  • A. И. Степанов Special Design and Construction Bureau SDCB "Technolog"
  • Д. В. Дашко Special Design and Construction Bureau SDCB "Technolog"
  • А. А. Астратьев Special Design and Construction Bureau SDCB "Technolog"

DOI:

https://doi.org/10.1007/446

Keywords:

furazan, furoxan, glyoximes, 1, 2, 5-oxadiazole, 5-oxadiazole 2-oxide, catalytic hydrogenation

Abstract

The reduction of 3,4-bis(4-R-furazan-3-yl)furoxans with hydrazine or hydrogen in the presence of palladium on carbon resulted in opening of the furoxan ring and formation of (Z,E)-dioximes of 1,2-di(4-R-furazan-3-yl)ethane-1,2-diones in high yield. The reactivity of the resultant glyoximes was studied.

Authors: A. I. Stepanov, D. V. Dashko, and A. A. Astrat'ev

English Translation in Chemistry of Heterocyclic Compounds, 2013, 49 (5), pp 776-790

http://link.springer.com/article/10.1007/s10593-013-1309-y

Author Biographies

A. И. Степанов, Special Design and Construction Bureau SDCB "Technolog"

начальник технологической лаборатории

Андрей Игоревич Степанов

Д. В. Дашко, Special Design and Construction Bureau SDCB "Technolog"

начальник отдела

Дмитрий Владимирович Дашко

А. А. Астратьев, Special Design and Construction Bureau SDCB "Technolog"

заместитель директора

Александр Александрович Астратьев

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Published

2013-05-09

Issue

No. 5 (2013)

Section

Original Papers