SYNTHESIS OF 1H-1,5,7-TRIAZACYCLOPENTA[<i>c</i>,<i>d</i>]PHENALENES BY THE ELECTROPHILIC AMINATION OF PERIMIDINES USING SODIUM AZIDE IN PPA
DOI:
https://doi.org/10.1007/5258Keywords:
sodium azide, perimidines, PPA, 1H-1, 5, 7-triazacyclopenta[c, d]phenalenes, 1, 3, 5-triazines, aminationAbstract
A method was developed for the synthesis of 1H-1,5,7-triazacyclopenta[c,d]phenalenes by the electrophilic amination of perimidines using the new sodium azide/PPA reagent system and a subsequent one-pot reaction with 1,3,5-triazines. A multicomponent variant of this reaction is possible in the case of 2,4,6-trimethyl- and 2,4,6-triphenyl-1,3,5-triazines.
How to Cite
Aksenov, A. V.; Lyakhovnenko, A. S.; Andrienko, A. V. Chem. Heterocycl. Compd. 2011, 46, 1266. [Khim. Geterotsikl. Soedin. 2010, 1563.]