HYPERVALENT IODINE IN THE STRUCTURE OF N-HETEROCYCLES: SYNTHESIS, STRUCTURE, AND APPLICATION IN ORGANIC SYNTHESIS

Authors

  • Юлия А. Власенко Research School of Chemical and Biomedical Technologies, National Research Tomsk Polytechnic University, 30 Lenina Ave., Tomsk 634050
  • Мехман С. Юсубов Research School of Chemical and Biomedical Technologies, National Research Tomsk Polytechnic University, 30 Lenina Ave., Tomsk 634050
  • Александр Шафир Department of Biological Chemistry, Institute for Advanced Chemistry of Catalonia, 18–26 Jordi Girona, Barcelona 08034
  • Павел С. Постников Research School of Chemical and Biomedical Technologies, National Research Tomsk Polytechnic University, 30 Lenina Ave., Tomsk 634050

DOI:

https://doi.org/10.1007/5728

Keywords:

hypervalent iodine, organoiodine compounds, pseudoheterocyclic compounds, oxidation, nitrogen–iodine bond

Abstract

The review is devoted to one of the most important trends in the chemistry of hypervalent iodine – synthesis, structure, and properties of heterocyclic and pseudoheterocyclic systems based on λ3- and λ5-iodanes. Among the variety of cyclic reagents based on hypervalent iodine, special attention has recently been paid to iodanes having close contact between I and N atoms. Within the framework of this review, the authors have analyzed the methods of synthesis, structural features of these reagents, and their synthetic applications. The review includes more than 100 literature sources, mainly covering publications from 1990 to 2020 and key research from earlier years.

Authors: Yulia А. Vlasenko, Mehman S. Yusubov, Alexandr Shafir*, Pavel S. Postnikov*

Author Biographies

Юлия А. Власенко, Research School of Chemical and Biomedical Technologies, National Research Tomsk Polytechnic University, 30 Lenina Ave., Tomsk 634050

Юлия Александровна Власенко

аспирант, инженер Исследовательской школы химических и биомедицинских технологий

Мехман С. Юсубов, Research School of Chemical and Biomedical Technologies, National Research Tomsk Polytechnic University, 30 Lenina Ave., Tomsk 634050

Мехман Сулейман оглы Юсубов

Проректор по науке и инновациям Томского политехнического университета

Александр Шафир, Department of Biological Chemistry, Institute for Advanced Chemistry of Catalonia, 18–26 Jordi Girona, Barcelona 08034

Исследователь Института продвинутой химии Каталонии

Павел С. Постников, Research School of Chemical and Biomedical Technologies, National Research Tomsk Polytechnic University, 30 Lenina Ave., Tomsk 634050

Павел Сергеевич Постников

доцент Исследовательской школы химических и биомедицинских технологий

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Published

2020-07-31

Issue

Vol. 56 No. 7 (2020): Synthesis and transformations of heterocycles under electrophilic conditions

Section

Review Articles