3,4-BIS(BROMOMETHYL)FURAZAN AND ITS <i>N</i>-OXIDE

Authors

  • Артем В. Хахалев N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Ave., Moscow 119991
  • Алексей А. Анисимов Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky Ave., Moscow 119991
  • Алексей Б. Шереметев N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Ave., Moscow 119991

DOI:

https://doi.org/10.1007/6612

Keywords:

dimethylglyoxime, furazan, furoxan, bromination, cyclization

Abstract

The conditions for bromination of the methyl groups of dimethylglyoxime were found, and the resulting product, a 1,4-dioxane solvate of bis(bromomethyl)glyoxime, was used as a precursor for heterocyclizations involving cyclodehydration or oxidative cyclization of the oxime groups leading to the formation of furazan and furoxan rings, respectively.

Authors: Artem V. Khakhalev, Aleksei А. Anisimov, Aleksei B. Sheremetev

Author Biography

Алексей Б. Шереметев, N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Ave., Moscow 119991

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Published

2022-05-18

Issue

Vol. 58 No. 4/5 (2022)

Section

Short Communications