SYNTHESIS AND X-RAY STRUCTURAL INVESTIGATION OF BISMUTH 2-METHYL-8-QUINOLINESELENOLATE Bi[C<sub>9</sub>H<sub>5</sub>(CH<sub>3</sub>)NSe]<sub>3</sub>

Authors

  • Э. Силинь Institute of Inorganic Chemistry, Riga Technical University, Salaspils LV-2169
  • С. Беляков Latvian Institute of Organic Synthesis, Riga LV-1006
  • Я. Ашакс Institute of Inorganic Chemistry, Riga Technical University, Salaspils LV-2169
  • А. Токмаков Latvian Institute of Organic Synthesis, Riga LV-1006
  • Л. Печ Institute of Inorganic Chemistry, Riga Technical University, Salaspils LV-2169
  • Д. Зарума Institute of Inorganic Chemistry, Riga Technical University, Salaspils LV-2169

DOI:

https://doi.org/10.1007/6656

Keywords:

bismuth(III), antimony(III), and arsenic(III) 2-methyl-8-quinolineselenolates and 2-methyl-8-quinolinethiolates, unshared electron pair, X-ray structural analysis

Abstract

Bismuth 2-methyl-8-quinolineselenolate, Bi[C<sub>9</sub>H<sub>5</sub>(CH<sub>3</sub>)NSe]<sub>3</sub>, was synthesized. X-ray analysis was used to determine the structure of  this  complex.  The crystal chemistry of bismuth(III), antimony(III), and arsenic(III) 2-methyl-8-quinolineselenolates and 2-methyl-8-quinolinethiolates was discussed relative to the effect of going from Se to S as the  ligand atoms and presence of a methyl group at C-2 of the
quinoline system and unshared electron pair of the central atom in the complex.

How to Cite
Silina, E.; Belyakov, S.; Ashaks, J.; Tokmakov, A.; Pech, L.; Zaruma, D.  Chem. Heterocycl. Compd. 2009, 45, 860. [Khim. Geterotsikl. Soedin. 2009, 1080.]

For this article in the English edition see DOI 10.1007/s10593-009-0347-y


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Published

2022-03-03

Issue

No. 7 (2009)

Section

Original Papers