SYNTHESIS AND STRUCTURE OF BISMUTH 8-QUINOLINESELENOLATE Bi(C<sub>9</sub>H<sub>6</sub>NSe)<sub>3</sub>

Authors

  • Э. Силинь Institute of Inorganic Chemistry, Riga Technical University, Salaspils LV-2169
  • Я. Ашакс Institute of Inorganic Chemistry, Riga Technical University, Salaspils LV-2169
  • С. Беляков Latvian Institute of Organic Synthesis, Riga LV-1006
  • А. Токмаков Latvian Institute of Organic Synthesis, Riga LV-1006
  • Л. Печ Institute of Inorganic Chemistry, Riga Technical University, Salaspils LV-2169
  • Д. Зарума Institute of Inorganic Chemistry, Riga Technical University, Salaspils LV-2169

DOI:

https://doi.org/10.1007/7321

Keywords:

bismuth chelate compounds, bismuth 8-quinolineselenolate, bismuth 8-quinolinethiolate, unshared electron pair (UEP), X-ray diffraction structural analysis

Abstract

Bismuth 8-quinolineselenolate Bi(C9H6NSe)3 was synthesized. The molecular and crystal structure of this compound was determined by X-ray diffraction  structural analysis. The effect of replacing the ligand atoms Se→S and the role of the unshared electron pair on the formation of the coordination polyhedron of the central bismuth atom in bismuth(III) 8-quinolineselenolate and bismuth(III)
8-quinolinethiolate, which are complexes of a Group V p-element in an incomplete valence state was discussed.

How to Cite
Siliņa, E.; Ashaks, J.; Belyakov, S.; Tokmakov, A.; Pech, L.; Zaruma, D.  Chem. Heterocycl. Compd. 2007, 43, 1582. [Khim. Geterotsikl. Soedin. 2007, 1866.]

For this article in the English edition see DOI 10.1007/s10593-007-0244-1

 

Downloads

Published

2023-01-17

Issue

No. 12 (2007)

Section

Original Papers