THE REACTION OF N-R-2-CYANOTHIOACETAMIDES WITH ETHYL[(ARYL)HYDRAZONO]CHLOROACETATES

Authors

  • В. Н. Брицун Organic Chemistry Institute, Ukraine National Academy of Sciences, Kiev 02660
  • В. Н. Боднар Organic Chemistry Institute, Ukraine National Academy of Sciences, Kiev 02660
  • М. О. Лозинский Organic Chemistry Institute, Ukraine National Academy of Sciences, Kiev 02660

DOI:

https://doi.org/10.1007/7707

Keywords:

N-R-2-cyanothioacetamide, ethyl [(aryl)hydrazono]chloroacetate, 1, 3, 4-thiadiazole, thiazolidin-4-one, thiophene, cyclization

Abstract

Depending on the nature of the substituents in the starting reagents and the basicity of the medium the cyclization of N-R-2-cyanothioacetamides with  ethyl [(aryl)hydrazono]chloroacetates gives 3-aryl-2-cyanomethylidene-5-ethoxycarbonyl-1,3,4-thiadiazoles, 5-arylhydrazono-2-cyanomethylidene-3-phenyl-thiazolidin-4-ones, di[(aryl)hydrazono](ethoxycarbonylmethyl) sulfides, and 5-amino-3-cyano-2-phenyl-
amino-4-(N-phenylaminothiocarbonyl)thiophene.

How to Cite
Britsun, V. N.; Bodnar, V. N.; Lozinskii, M. O.  Chem. Heterocycl. Compd. 2007, 43, 93. [Khim. Geterotsikl. Soedin. 2007, 109.]

For this article in the English edition see DOI 10.1007/s10593-007-0014-0


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Published

2023-04-06

Issue

No. 1 (2007)

Section

Original Papers