CONDENSED TETRAZOLO-1,3,5-TRIAZINES. 4. SYNTHESIS OF SALTS OF 5-AMINOTETRAZOLO[1,5-<i>a</i>]-1,3,5-TRIAZIN-7-ONE

Authors

  • В. В. Бахарев Samara State Technical University, Samara 443100
  • А. А. Гидаспов Samara State Technical University, Samara 443100
  • Д. Б. Криволапов A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Science Center of the Russian Academy of Sciences, Kazan 420088
  • Е. В. Миронова A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Science Center of the Russian Academy of Sciences, Kazan 420088
  • И. А. Литвинов A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Science Center of the Russian Academy of Sciences, Kazan 420088

DOI:

https://doi.org/10.1007/7844

Keywords:

2-amino-4-azido-1, 3, 5-triazin-6(1H)-one, 2-amino-4, 6-bis(trinitromethyl)-1, 5-triazines, salts of 5-aminotetrazolo[1, 5-a]-1, 5-triazin-7-one, azido-tetrazole tautomeric conversion

Abstract

2-Amino-4-azido-1,3,5-triazin-6(1H)-ones were synthesized by successive substitution  of  the trinitromethyl groups in 2-amino-4,6-bis(trinitromethyl)-1,3,5-triazines under the influence of azide and nitrite ions. Interaction of 2-amino-4-azido-1,3,5-triazin-6(1H)-ones with bases led to the azido-tetrazole tautomeric conversion give salts of 5-aminotetrazolo[1,5-a]-1,3,5-triazin-7-one.

How to Cite
Bakharev, V. V.; Ghidaspov, A. A.; Krivolapov, D. B.; Mironova, E. V.; Litvinov, I. A.  Chem. Heterocycl. Compd. 2006, 42, 1051. [Khim. Geterotsikl. Soedin. 2006, 1211.]

For this article in the English edition see DOI 10.1007/s10593-006-0203-2


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Published

2023-05-26

Issue

No. 8 (2006)

Section

Original Papers