ATOM-ECONOMIC SYNTHESIS OF NEW IMIDAZOLES AND BENZIMIDAZOLES WITH THIOPHOSPHORYL AND HYDROXYL GROUPS

Authors

  • Н. И. Иванова A. E. Favorsky Irkutsk Institute of Chemistry, Irkutsk 664033
  • Л. В. Байкалова A. E. Favorsky Irkutsk Institute of Chemistry, Irkutsk 664033
  • Н. А. Коновалова A. E. Favorsky Irkutsk Institute of Chemistry, Irkutsk 664033
  • И. А. Зырянова A. E. Favorsky Irkutsk Institute of Chemistry, Irkutsk 664033
  • А. И. Албанов A. E. Favorsky Irkutsk Institute of Chemistry, Irkutsk 664033
  • Л. М. Синеговская A. E. Favorsky Irkutsk Institute of Chemistry, Irkutsk 664033
  • В. А. Кухарева A. E. Favorsky Irkutsk Institute of Chemistry, Irkutsk 664033
  • А. А. Татаринова A. E. Favorsky Irkutsk Institute of Chemistry, Irkutsk 664033
  • Н. Д. Aвсеенко A. E. Favorsky Irkutsk Institute of Chemistry, Irkutsk 664033
  • Б. Г. Сухов A. E. Favorsky Irkutsk Institute of Chemistry, Irkutsk 664033
  • Н. К. Гусарова A. E. Favorsky Irkutsk Institute of Chemistry, Irkutsk 664033
  • Б. А. Трофимов A. E. Favorsky Irkutsk Institute of Chemistry, Irkutsk 664033

DOI:

https://doi.org/10.1007/8344

Keywords:

bis(2-phenylethyl)phosphine sulfide, 2-[bis(2-phenylethyl)thiophosphorylhydroxymethyl]-1-ethyl(vinyl)imidazoles, hydrochlorides of 2-[bis(2-phenylethyl)thiophosphorylhydroxymethyl]-1-ethyl(vinyl)imidazoles, 2-formyl-1-organylimidazoles, 2-formyl-1-organylbenzimidazoles, hydrothiophosphorylation

Abstract

Nucleophilic addition of secondary phosphine sulfides to an aldehyde of the azole series occurs under noncatalytic conditions in THF at room temperature and enables the preparation in high yield of imidazoles and benzimidazoles with thiophosphoryl and hydroxyl groups, which are promising building blocks for organic synthesis and polydentate ligands for metal complexes.

How to Cite
Ivanova, N. I.; Baikalova, L. V.; Konovalova, N. A.; Zyryanova, I. A.; Albanov, A. I.;
Sinegovskaya, L. M.; Kukhareva, V. A.;  Tatarinova, A. A.; Avseenko, N. D.; Sukhov, B. G.; Gusarova, N. K.; Trofimov, B. A.  Chem. Heterocycl. Compd. 2005, 41, 317. [Khim. Geterotsikl. Soedin. 2005, 365.]

For this article in the English edition, see DOI 10.1007/s10593-005-0150-3


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Published

2023-11-27

Issue

No. 3 (2005)

Section

Original Papers