CHARACTERISTICS OF THE DISSOCIATIVE IONIZATION OF 9-ARYL(HETARYL)-3,3,6,6-TETRAMETHYLDECAHYDROACRIDINE-1,8-DIONES UNDER THE INFLUENCE OF ELECTRON IMPACT

Authors

  • Yu. M. Shchekotikhin "Nita-Farm", Saratov 410005
  • T. G. Nickolaeva Saratov State University, Saratov 410026

Keywords:

3,3,6,6-tetramethyl-9-R-decahydroacridine-1,8-diones, dissociative ionization, retrodiene decomposition

Abstract

The mass spectra of 9-aryl(hetaryl)-3,3,6,6-tetramethyldecahydroacridine-1,8-diones have been studied and the basic directions of their dissociative ionization under the influence of electron impact have been elucidated. It has been shown that the decomposition pathways of decahydroacridine-1,8-diones depend on the nature of the substituents at position 10 and is connected with the preferential formation of a pyridinium structure with subsequent retrodiene decomposition of the molecules.

How to Cite
Shchekotikhin, Yu. M.; Nickolaeva, T. G. Chem. Heterocycl. Compd. 2004, 40, 1031. [Khim. Geterotsikl. Soedin. 2004, 1193.]

For this article in the English edition, see DOI 10.1023/B:COHC.0000046693.85136.ac

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Published

2004-08-25

Issue

No. 8 (2004)

Section

Original Papers