SYNTHESIS OF LARIAT DIAZACROWN ETHERS WITH TERMINAL AMINO GROUPS IN THE SIDE CHAINS

Authors

  • Н. Г. Лукьяненко A. V. Bogatsky Physico-Chemical Institute, Odessa 65080
  • Т. И. Кириченко A. V. Bogatsky Physico-Chemical Institute, Odessa 65080
  • С. В. Щербаков A. V. Bogatsky Physico-Chemical Institute, Odessa 65080

Keywords:

diazacrown ethers, N,N'-substituted, terminal amino groups, lariat effect

Abstract

Treatment of diazacrown ethers with N-(haloalkyl)- and N-(haloethoxy)phthalimides gives the corresponding N,N'- substituted diazacrown ether. Hydrazinolysis of the latter then gives diazacrown ethers with terminal primary amino groups in the side chain. Their reductive methylation using formaldehyde in formic acid gives the dimethylamino derivatives. The presence of a lariat effect was demonstrated by treating the compounds obtained with picrates of alkali and alkaline-earth metals.

How to Cite
Lukyanenko, N. G.; Kirichenko, T. I.; Shcherbakov, S. V. Chem. Heterocycl. Compd. 2004, 40, 343. [Khim. Geterotsikl. Soedin. 2004, 421.]

For this article in the English edition, see DOI 10.1023/B:COHC.0000028631.81899.15

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Published

2004-03-25

Issue

No. 3 (2004)

Section

Original Papers