INTERACTION OF 5-METHOXY-4-AZATRICYCLO[4.3.1.1<sup>3,8</sup>]UNDEC-4-ENE WITH NITROGEN-CONTAINING NUCLEOPHILES

Authors

  • Е. А. Князева Samara State Technological University
  • М. Ю. Скоморохов Samara State Technological University
  • Д. В. Осипов Samara State Technological University
  • Ю. Н. Климочкин Samara State Technological University

DOI:

https://doi.org/10.1007/910

Keywords:

6, 7, 8, 9, 10, 11-hexahydro-5H-5, 11-dimethano[1, 2, 4]triazolo[4, 3-a]azocin-3-one, lactim ethers, 5-methoxy-4-azatricyclo-[4.3.1.13, 8]undec-4-ene, N-methyl lactam, N-alkylation, O-alkylation

Abstract

The interaction of 5-methoxy-4-azatricyclo[4.3.1.13,8]undec-4-ene with acid hydrazides has been studied. It has been established that its reaction with methoxycarbonylhydrazine leads to the formation of 6,7,8,9,10,11-hexahydro-5H-5,9:7,11-dimethano[1,2,4]triazolo[4,3-a]azocin-3-one. Special features of the alkylation of this substrate under various conditions have been studied.

Authors: E. A. Knyazeva, M. Yu. Skomorokhov, D. V. Osipov, and Yu. N. Klimochkin

English Translation in Chemistry of Heterocyclic Compounds, 2013, 48 (10), pp 1517-1521

http://link.springer.com/article/10.1007/s10593-013-1166-8

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Published

2013-08-28

Issue

No. 10 (2012)

Section

Original Papers