CATALYTIC OXIDATION OF FURAN AND HYDROFURAN COMPOUNDS. 7. PRODUCTION OF 2(5H)-FURANONE BY OXIDATION OF FURFURAL WITH HYDROGEN PEROXIDE AND SOME OF ITS TRANSFORMATIONS IN AQUEOUS SOLUTIONS

Authors

  • Л. А. Бадовская Kuban State Technological University, Krasnodar
  • В. М. Латашко Kuban State Technological University, Krasnodar
  • В. В. Посконин Kuban State Technological University, Krasnodar
  • Е. П. Грунская Kuban State Technological University, Krasnodar
  • З. И. Тюхтенева Kuban State Technological University, Krasnodar
  • С. Г. Рудакова Kuban State Technological University, Krasnodar
  • С. А. Пестунова Kuban State Technological University, Krasnodar
  • А. В. Саркисян Kuban State Technological University, Krasnodar

Keywords:

2(5H)-furanone, hydrolysis, complexation, oxidation

Abstract

Data on the synthesis of 2(5H)-furanone by the oxidation of furfural with aqueous hydrogen peroxide under the conditions of autocatalysis by the accumulating acids and also in the presence of catalytic amounts of Cr(VI) and Mo(VI) compounds are presented. Some transformations of 2(5H)-furanone in aqueous solutions are studied: Hydrolysis, oxidation by potassium permanganate, complex formation with the ions of certain d-metals.

How to Cite
Badovskaya, L. A.; Latashko, V. M.; Poskonin, V. V.; Grunskaya, E. P.; Tyukhteneva, Z. I.; Rudakova, S. G.;  Pestunova, S. A.; Sarkisyan, A. V. Chem. Heterocycl. Compd. 2002, 38, 1040. [Khim. Geterotsikl. Soedin. 2002, 1194.]

For this article in the English edition, see DOI https://doi.org/10.1023/A:1021288711593

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Published

2002-09-25

Issue

No. 9 (2002)

Section

Original Papers