PECULIARITIES OF 4-METHALLYL-5-METHALLYLAMINO-1,2,4-TRIAZOLE-3-THIONE HALOGENATION
DOI:
https://doi.org/10.1007/5003Ключевые слова:
[1, 3]thiazolo[2, 3-c][1, 2, 4]triazole, 1, 4-triazole, 4]triazolo[3, 4-b][1, 3]thiazine, electrophilic cyclization, halogenationАннотация
Bromination and iodination of 4-methallyl-5-methallylamino-1,2,4-triazole-3-thione lead to the annulation of five- and six-membered thiazaheterocycles, respectively. The usage of halogen excess does not give the product of 5-methallylamino group cyclization – the product of the bromine addition was isolated.
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2019-05-22
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