<i>N</i>-(ALKOXY)- AND <i>N</i>-(ACYLOXY)PHTHALIMIDES IN ORGANIC SYNTHESIS: FREE RADICAL SYNTHETIC APPROACHES AND APPLICATIONS

Авторы

  • Alexander S. Budnikov N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Ave., Moscow 119991, Russia
  • Igor B. Krylov N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Ave., Moscow 119991, Russia

DOI:

https://doi.org/10.1007/5482

Ключевые слова:

N-hydroxypthalimide, cross-dehydrogenative coupling, free radicals, photoredox catalysis

Аннотация

The microreview covers selected examples of the free radical cross-dehydrogenative C–O coupling of various CH reagents with N-hydroxyphthalimide leading to N-(alkoxy)- and N-(acyloxy)phthalimides.
Synthetic applications of the latter associated with the cleavage of N–O bond leading to the O-, N- and C-centered free radicals are also reviewed.

Биография автора

Igor B. Krylov, N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Ave., Moscow 119991, Russia

Laboratory for Studies of Homolytic Reactions, PhD, Senior Researcher

Загрузки

Опубликован

2020-01-31

Выпуск

Том 56 № 1 (2020)

Раздел

Гетероциклы в фокусе