PHOTOCHEMICAL SYNTHESIS OF NOVEL NAPHTHO[1,2-<i>b</i>]BENZOFURAN DERIVATIVES FROM 2,3-DISUBSTITUTED BENZOFURANS

Авторы

  • Boris V. Lichitsky N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Ave., Moscow 119991, Russia
  • Constantine V. Milyutin N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Ave., Moscow 119991, Russia
  • Valeriya G. Melekhina N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Ave., Moscow 119991, Russia
  • Artem N. Fakhrutdinov N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Ave., Moscow 119991, Russia
  • Andrey N. Komogortsev N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Ave., Moscow 119991, Russia
  • Michail M. Krayushkin N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Ave., Moscow 119991, Russia

DOI:

https://doi.org/10.1007/5983

Ключевые слова:

dibenzo[b, d]furans, naphtho[1, 2-b]benzofurans, terarylenes, intramolecular dehydration, photocyclization.

Аннотация

A novel approach to the synthesis of naphtho[1,2-b]benzofuran derivatives based on the photochemical reaction of 2,3-disubstituted benzofurans was developed. The studied process includes the photocyclization of the hexatriene system and subsequent aromatization of benzene ring via elimination of water molecule. The starting terarylenes were prepared via a new three-component condensation of phenols, arylglyoxals, and cyclic 1,3-diketones.

Загрузки

Опубликован

2021-01-26

Выпуск

Том 57 № 1 (2021)

Раздел

Оригинальные статьи