PHENOXATHIIN CHEMISTRY. REMARKS CONCERNING THE BENZOYLATION REACTION OF PHENOXATHIIN

Authors

  • G. Loloiu Faculty of Сhemistry, Org. Chem. Dept., University of Bucharest, 90-92 Panduri Road, 76233
  • C. Draghici Faculty of Сhemistry, Org. Chem. Dept., University of Bucharest, 90-92 Panduri Road, 76233
  • T. Loloiu Faculty of Сhemistry, Org. Chem. Dept., University of Bucharest, 90-92 Panduri Road, 76233
  • О. Maior Faculty of Сhemistry, Org. Chem. Dept., University of Bucharest, 90-92 Panduri Road, 76233

Abstract

Benzoylation of phenoxathiin leads to a mixture of 2- and 3-benzoylphеnoxathiins. Starting from 3-phenoxathiinсarbоnyl chloride and benzene in presence of anhydrous aluminum chloride, 2-benzoylрhеnoxаthiin was obtained, instead of 3-substituted isomer. Treating 3-benzoylphеnоxathiin with aluminum chloride and hydrogen chloride a rearran-gement reaction took place, leading to 2-bеnzoylрhеnoxathiin.

How to Cite
Loloiu, G.; Draghici, C.; Loloiu, T.; Maior, O. Chem. Heterocycl. Compd. 1998, 34, 1. [Khim. Geterotsikl. Soedin. 1998, 34, 1.]

For this article in the English edition, see DOI https://doi.org/10.1007/BF02251698

Downloads

Published

1998-07-25

Issue

No. 7 (1998)

Section

Original Papers