Allylboration of isatin and 2,3-dioxopyrrolo[2,1-<i>a</i>]isoquinolines

Authors

  • А. Г. Михайловский Institute of Technical Chemistry, Ural Branch, Russian Academy Sciences, Perm' 614000
  • А. B. Игнатенко N. D. Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences, Moscow 117913
  • Ю. H. Бубнов Institute of Technical Chemistry, Ural Branch, Russian Academy Sciences, Perm' 614000

Abstract

The reaction of triallylboron with isatin and derivatives 2,3-dioxopyrrolo[2,1-a]isoquinolines at room temperature proceeds regiospecifically at the ketone group to give the corresponding homoallyl alcohol. One of these, which contains a lactam and an amide in its structure, was reduced with lithium tetrahydroaluminate to a diamine.

How to Cite
Mikhailovskii, A. G.; Ignatenko, A. V.; Bubnov, Y. N. Chem. Heterocycl. Compd. 1998, 34, 785. [Khim. Geterotsikl. Soedin. 1998, 34, 908.]

For this article in the English edition, see DOI https://doi.org/10.1007/BF02251683

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Published

1998-07-25

Issue

No. 7 (1998)

Section

Original Papers