Adamantylazoles. Acid-catalyzed adamantylation of 1,2,4-triazoles

Authors

  • В. В. Сараев St. Petersburg State Technological Institute, St. Petersburg 198013
  • Т. П. Канакина St. Petersburg State Technological Institute, St. Petersburg 198013
  • М. C. Певзнер St. Petersburg State Technological Institute, St. Petersburg 198013
  • E. Л. Голод St. Petersburg State Technological Institute, St. Petersburg 198013
  • Б. И. Уграк N. D. Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences, 117913 Moscow
  • B. B. Качала N. D. Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences, 117913 Moscow

Abstract

The reaction of 1-adamantanol with 1,2,4-triazole in sulfuric acid forms 1-adamantyl derivatives. In boiling chloroform containing traces of sulfuric acid, a mixture of isomeric N-adamantyl-1,2,4-triazoles is obtained. It is shown that 1-adamantyl carbocation is formed at a sulfuric acid concentration above 70%.

How to Cite
Saraev, V. V.; Kanakina, T. P.; Pevzner, M. S.; Golod, E. L.; Ugrak, B. I.; Kachala, V. V. Chem. Heterocycl. Compd. 1996, 32, 928. [Khim. Geterotsikl. Soedin. 1996, 1078.]

For this article in the English edition, see DOI https://doi.org/10.1007/BF01176969

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Published

1996-08-25

Issue

No. 8 (1996)

Section

Original Papers