ADDITION OF NITRILE OXIDES TO N-ALLYLSACCHARIN

Authors

  • В. Дирненс Latvian Institute of Organic Synthesis, Riga LV-1006
  • С. Беляков Latvian Institute of Organic Synthesis, Riga LV-1006
  • Э. Лукевиц Latvian Institute of Organic Synthesis, Riga LV-1006

DOI:

https://doi.org/10.1007/8356

Keywords:

N-allylsaccharin, isoxazolines, nitrile oxides

Abstract

The addition of nitrile oxides to N-allylsaccharin  has been studied and it has been shown  that  the reaction occurs regiospecifically to form a 5-substituted isomer. The molecular structure  of 2-{5-[(3-methyl)isoxazolin-2-yl]methyl}-3-oxo-2,3-dihydrobenz[d]isothiazole 1,1-dioxide has been determined by X-ray analysis. A feature of the crystal of this compound is the presence of a supersymmetrical crystalline structure with two  independent molecules associated by a center of pseudoinversion.

How to Cite
Dirnens, V.; Belyakov, S.; Lukevics, E. Chem. Heterocycl. Compd. 2005, 41, 393. [Khim. Geterotsikl. Soedin. 2005, 450.]

For this article in the English edition, see DOI 10.1007/s10593-005-0160-1


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Published

2023-11-29

Issue

No. 3 (2005)

Section

Original Papers