REACTION OF 2-CHLORO-5-(CHLOROMETHYL)THIOPHENE WITH MONOETHANOLAMINE VINYL ETHER

Authors

  • Л. К. Паперная Irkutsk A. E. Favorsky Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk 664033
  • Э. Н. Дерягина Irkutsk A. E. Favorsky Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk 664033
  • А. И. Албанов Irkutsk A. E. Favorsky Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk 664033

Keywords:

monoethanolamine vinyl ether, N-(5-chloro-2-thienylmethyl)-N-(2-vinyloxyethyl)amine, N,N-bis(5-chloro-2-thienylmethyl)-N-(2-hydroxyethyl)ammonium chloride, 2-chloro-5-(chloromethyl)thiophene, reactions

Abstract

At the alkylation of monoethanolamine vinyl ether with 2-chloro-5-(chloromethyl)thiophene in ethyl alcohol (60-70°C) a product of disubstitution and transvinylation, viz. N,N-bis(5-chloro-2-thienylmethyl)-N-(2-hydroxyethyl)ammonium chloride is formed. The analogous reaction in the absence of solvent proceeds with the formation of N-(5-chloro-2-thienylmethyl)-N-(2-vinyloxyethyl)amine.

How to Cite
Papernaya, L. K.; Deryagina, E. N.; Albanov, A. I. Chem. Heterocycl. Compd. 2002, 38, 1052. [Khim. Geterotsikl. Soedin. 2002, 1207.]

For this article in the English edition, see DOI https://doi.org/10.1023/A:1021292812502

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Published

2002-09-25

Issue

No. 9 (2002)

Section

Original Papers