INVESTIGATIONS ON 2,3'-BIQUINOLYLS. 15*. REGIOSELECTIVITY OF THE ADDITION OF NITROMETHANE ANION TO 1'-ALKYL-3'-(2-QUINOLYL)QUINOLINIUM HALIDES
Keywords:
1'-R-4'-nitromethyl-1',4'-dihydro-2,3'-biquinolyls, 1'-phenacyl-1',4'-dihydro-2,3'-biquinolyls, 1'-R-3'-(2-quinolyl)quinolinium halide, alkylation, nucleophilic additionAbstract
1'-R-3'-(2-Quinolyl)quinolinium halides react with nitromethane forming products of addition at the position 4', the 1'-R-4'-nitromethyl-1',4'-dihydro-2,3'-biquinolyls. A method has been developed for the synthesis of 1'-phenacyl-1',4'-dihydro-2,3'-biquinolyls based on the alkylation of 1',4'-dihydro-2,3'-biquinolyl with halogen derivatives in DMF.
How to Cite
Aksenov, A. V. Chem. Heterocycl. Compd. 2003, 39, 756. [Khim. Geterotsikl. Soedin. 2003, 884.]
For this article in the English edition, see DOI https://doi.org/10.1023/A:1025695028734
